Vinyl is a popular material used in many building and construction
products. Because of its versatility, vinyl is found in both rigid and
flexible applications, manufactured by extrusion or calendering, and
used for both interior and exterior products, in both residential and
commercial/industrial structures.
Stabilizers are added to vinyl compounds both to avoid degradation
in the manufacturing process, and to enhance the performance of the
final product. In North America, tin stabilizers are the dominant choice
in rigid vinyl applications such as pipe and siding. They also are used
in gutter systems, window profiles, interior doors and molding, fencing,
decking and railing, and some flexible products such as vinyl flooring
and roofing membranes. In addition, tins are found in foamed vinyl applications
such as decorative trim and shutters, consumer storage systems and residential,
commercial and industrial building systems. They also are found in indoor
window coverings such as vertical blinds.
Tin stabilizers are a cost-effective solution to the high demands
of the building and construction industry. Tins enhance the manufacturing
process as well as the performance characteristics of the final product.
Due to the breadth of applications and processes involved in making
these vinyl products, a wide variety of tin stabilizers can be used.
A number of factors determine which stabilizer is best for a particular
application. Because of their versatility and the selection available
in the octyl-, methyl- and butyltin categories, tin stabilizers can
be formulated specifically for the performance characteristics required
in the end product. For example, in vinyl siding, a less expensive tin
stabilizer can be used in the substrate while a higher performance tin
stabilizer that meets demanding requirements for weather resistance
and color retention can be used in the capstock.
In addition to enhancing the durability of the final product, tin
stabilizers are critical to the manufacturing process. Siding is produced
by extrusion, a high-heat and high-speed process, and tin stabilizers
contribute to the efficiency of the manufacturing process by improving
output rates while providing stability during extreme processing temperatures.
Another key factor for building products is the quality of the surface
and color. In window profiles, for example, tin stabilizers allow for
consistently whiter products that maintain their initial color. Tin
stabilizers are used in the topcoat for vinyl flooring because they
provide heat stability during the calendering process, which allows
the wear layer to be applied during thermal processing. In the final
product, they provide clarity so that the vivid colors and patterns
show through clearly and resist yellowing over time.
Because of the high demands of process shear and activation in foamed
vinyl applications, tin stabilizers are used to enhance the process
and the blowing agents. Tin stabilizers perform well under these rigorous
processing conditions. Their thermal stability and efficiency make it
possible for the manufacturer to create complex, multi-hollow shapes
in foamed or rigid vinyl extrusions, enhancing the thermal insulation
value of the final application. The result is profiles that are lightweight
but durable.
Product Safety
Tin stabilizers have been safely used in vinyl building and construction
products for more than 50 years. In recent years, some questions have
arisen about the migration of additives, including tins, from vinyl
products. Particularly in the case of interior products, such as vinyl
flooring, critics have raised concerns about the potential health impact
from human exposure. However, studies have clearly demonstrated that
the slight migration that could possibly occur from these products does
not pose a health risk.
Finally, where indoor air quality is a concern, low-odor stabilizers
have been developed and can be specified
End-of-life issues
Because they improve thermal stability, tin stabilizers make it easier
to recycle vinyl products by helping to reduce degradation during the
process steps required for recycling. Vinyl siding, for example, is
being recycled both by manufacturers (e.g., manufacturing off-cuttings
and construction site waste) and after consumer use, by removal and
recycling at the end of the product’s useful life. Vinyl products
also can be safely disposed of in landfills. Studies have shown that
levels of tin stabilizer leaching from vinyl products in landfill conditions
are very low, usually attributable to wash-off from the product’s
surface and pose no undue risk to human health or the environment.
January 2003